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Jay R. Brooks on Beer

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Historic Beer Birthday: Johan Kjeldahl

August 16, 2024 By Jay Brooks

carlsberg-crown
Today is the birthday of Johan Gustav Christoffer Thorsager Kjeldahl (August 16, 1849-July 18, 1900) He was a Danish chemist who developed a method for determining the amount of nitrogen in certain organic compounds using a laboratory technique which was named the Kjeldahl method after him.

Johan-Kjeldahl
Kjeldahl worked in Copenhagen at the Carlsberg Laboratory, associated with Carlsberg Brewery, where he was head of the Chemistry department from 1876 to 1900.

He was given the job to determine the amount of protein in the grain used in the malt industry. Less protein meant more beer. Kjeldahl found the answer was in developing a technique to determine nitrogen with accuracy but existing methods in analytical chemistry related to proteins and biochemistry at the time were far from accurate.

Haslund_Johan_KjeldA painting by Otto Haslund of Johan Kjeldahl.

His discovery became known as the Kjeldahl Method

Kjeldahl's_distillation

The method consists of heating a substance with sulphuric acid, which decomposes the organic substance by oxidation to liberate the reduced nitrogen as ammonium sulphate. In this step potassium sulphate is added to increase the boiling point of the medium (from 337 °C to 373 °C) . Chemical decomposition of the sample is complete when the initially very dark-coloured medium has become clear and colourless.

The solution is then distilled with a small quantity of sodium hydroxide, which converts the ammonium salt to ammonia. The amount of ammonia present, and thus the amount of nitrogen present in the sample, is determined by back titration. The end of the condenser is dipped into a solution of boric acid. The ammonia reacts with the acid and the remainder of the acid is then titrated with a sodium carbonate solution by way of a methyl orange pH indicator.

k-method
In practice, this analysis is largely automated; specific catalysts accelerate the decomposition. Originally, the catalyst of choice was mercuric oxide. However, while it was very effective, health concerns resulted in it being replaced by cupric sulfate. Cupric sulfate was not as efficient as mercuric oxide, and yielded lower protein results. It was soon supplemented with titanium dioxide, which is currently the approved catalyst in all of the methods of analysis for protein in the Official Methods and Recommended Practices of AOAC International.

And Velp Scientifica also has an explanation of his method, which is still in use today.

Carlsberg-Laboratory_435
Kjeldahl (center) in his laboratory.

Filed Under: Birthdays, Just For Fun, Related Pleasures Tagged With: Carlsberg, Denmark, History, Science, Science of Brewing

Historic Beer Birthday: Anders Jöns Ångström

August 13, 2024 By Jay Brooks

dark-side-of-moon
Today is the birthday of Anders Jöns Ångström (August 13, 1814–June 21, 1874). He “was a Swedish physicist and one of the founders of the science of spectroscopy.” The Ångström unit (1 Å = 10−10 m) in which the wavelengths of light and interatomic spacings in condensed matter are sometimes measured are named after him. Various types of spectroscopy are employed in the brewing industry.

Anders-Angstrom

Here’s a partial biography of Ångström from Wikipedia:

Anders Jonas Ångström was born in Medelpad to Johan Ångström, and schooled in Härnösand. He moved to Uppsala in 1833 and was educated at Uppsala University, where in 1839 he became docent in physics. In 1842 he went to the Stockholm Observatory to gain experience in practical astronomical work, and the following year he was appointed keeper of the Uppsala Astronomical Observatory.

Intrigued by terrestrial magnetism he recorded observations of fluctuations in magnetic intensity in various parts of Sweden, and was charged by the Stockholm Academy of Sciences with the task, not completed until shortly before his death, of working out the magnetic data obtained by HSwMS Eugenie on her voyage around the world in 1851 to 1853.

In 1858, he succeeded Adolph Ferdinand Svanberg in the chair of physics at Uppsala. His most important work was concerned with heat conduction and spectroscopy. In his optical researches, Optiska Undersökningar, presented to the Royal Swedish Academy of Sciences in 1853, he not only pointed out that the electric spark yields two superposed spectra, one from the metal of the electrode and the other from the gas in which it passes, but deduced from Leonhard Euler’s theory of resonance that an incandescent gas emits luminous rays of the same refrangibility as those it can absorb. This statement, as Sir Edward Sabine remarked when awarding him the Rumford medal of the Royal Society in 1872, contains a fundamental principle of spectrum analysis, and though overlooked for a number of years it entitles him to rank as one of the founders of spectroscopy.

Anders_Ångström_painting

This is the general definition of spectroscopy from Wikipedia:

Spectroscopy is the study of the interaction between matter and electromagnetic radiation. Historically, spectroscopy originated through the study of visible light dispersed according to its wavelength, by a prism. Later the concept was expanded greatly to include any interaction with radiative energy as a function of its wavelength or frequency. Spectroscopic data are often represented by an emission spectrum, a plot of the response of interest as a function of wavelength or frequency.

This abstract from the 2006 paper “Applications of Vibrational Spectroscopy in Brewing” gives an overview of their use by brewers.

The purpose of this chapter is to compile the literature concerning the applications of near‐infrared (NIR), mid‐infrared and Raman spectroscopy in the brewing industry. All these three techniques share the advantages that they are rapid, can be noninvasive and allow direct observation of specific molecular species. As for barley, many researchers have used the NIR reflectance on whole grains in malt evaluation. The NIR determination of α/β‐acids and hop storage index in baled hop samples is reported. NIR spectrophotometric methods have been developed for the determination of yeast concentration and activity in beer making. In addition to the applications in the laboratory of quality control, the overview concerns also the applications of infrared and Raman spectroscopy in monitoring of operation and process control at the essential steps of mashing and wort fermentation in brewery. The results obtained with a short wave NIR spectrophotometer are presented in comparison with long wave NIR spectrophotometers.

Brewers use spectrometers to measure a number of QC items throughout the brewing process.

Cover_Table1

To get a sense of how much spectrometers are used, this article promoting StellarNet, a company selling them, entitled Spectroscopy Prospects Brewing, is pretty thorough.

NIR-spectrometer-Beer

Filed Under: Birthdays, Just For Fun, Related Pleasures Tagged With: History, Science, Science of Brewing, Sweden

Historic Beer Birthday: Max Delbrück

June 16, 2024 By Jay Brooks

science

Today is the birthday of Max Emil Julius Delbrück (June 16, 1850-May 4, 1919). He was a German chemist who spent most of his career exploring the fermentation sciences.

max-delbruck

His Wikipedia entry is short:

Delbrück was born in Bergen auf Rügen. He studied chemistry in Berlin and in Greifswald. In 1872 he was made assistant at the Academy of Trades in Berlin; in 1887 he was appointed instructor at the Agricultural College, and in 1899 was given a full professorship. The researches, carried out in part by Delbrück himself, in part under his guidance, resulted in technical contributions of the highest value to the fermentation industries. He was one of the editors of the Zeitschrift für Spiritusindustrie (1867), and of the Wochenschrift für Brauerei. He died in Berlin, aged 68.

And here’s his entry from Today in Science:

Max Emil Julius Delbrück was a German chemist who spent a forty-five year career leading development in the fermentation industry. He established a school for distillation workers, a glass factory for the manufacture of reliable apparatus and instruments, and an experimental distillery. Giving attention to the raw resources, he founded teaching and experimental institutions to improve cultivation of potatoes and hops. He researched physiology of yeast and application in the process of fermentation, production of pure cultures, and the action of enzymes. He started the journals Zeitschrift fur Spiritus-Industrie (1867) and Wochenschrift für Brauerei, for the alcohol and brewery industries, which he co-edited.

Delbrück

Over the years, I’ve found a few great Delbrück quotes:

“Yeast is a machine.”

          — Max Delbrück, from an 1884 lecture

“With the sword of science and the armor of Practice, German beer will encircle the world.”

          — Max Delbrück, from an address about yeast and fermentation in the
               brewery, to the German Brewing Congress as Director of the Experimental
               and Teaching Institute for Brewing in Berlin, June 1884

Delbruck-memorial

Filed Under: Birthdays, Just For Fun, Related Pleasures Tagged With: Germany, History, Science, Science of Brewing

Historic Beer Birthday: Max Henius

June 16, 2024 By Jay Brooks

american-brewing-academy
Today is the birthday of Max Henius (June 16, 1859–November 15, 1935). He “was a Danish-American biochemist who specialized in the fermentation processes. Max Henius co-founded the American Academy of Brewing in Chicago.”

Henius-and-friends
Max Henius, at left, at Rebild, Denmark.

Here’s his biography, from Wikipedia:

Max Henius was born in Aalborg, Denmark. His parents were Isidor Henius (1820–1901) and Emilie (née Wasserzug) Henius (1839–1913), both Polish Jewish immigrants. His father, who was born in Thorn, West Prussia, now Torun, Poland, emigrated to Denmark in 1837 and continued his work for spirits distillers to improve and standardise production and later – 15 January 1846 – co-founded one distillery, Aalborg priviligerede Sirup- og Sprtitfabrik, that was later, together with several other distilleries, consolidated into De Danske Spritfabrikker in 1881, a Danish distillery which is now – since 2012 – part of the Norwegian Arcus Group, which closed the distillery in Aalborg in 2015, moving production to Norway instead. Isidor Henius also owned a small castle in Aalborg, now called Sohngaardsholm Slot. Since 2005, it has been the site of a gourmet restaurant.

Max Henius was educated at the Aalborg Latin School and went on to study at the Polytechnic Institute in Hanover, Germany He attended the University of Marburg, earning his Ph.D. degree in chemistry during 1881. His father sold the distillery that same year. Max Henius subsequently emigrated from Aalborg to the United States in 1881 at the age of 22, settling in Chicago. His younger brother, Erik S. Henius, (1863- 1926) remained in Denmark where he was Chairman of the Danish Export Association.

Initially he was employed by the Northern Pacific Railway on an assignment to test the waters between Fargo, North Dakota, and Bozeman, Montana. In 1886, he opened a drug store. Subsequently he formed Wahl & Henius, an institute for chemical and mechanical analysis, with his former schoolmate, Robert Wahl (1858-1937). Founded in 1891, the Chicago-based American Brewing Academy (later known as the Wahl-Henius Institute of Fermentology) was one of the premier brewing schools of the pre-prohibition era. This institute was later expanded with a brew master school that operated until 1921.

At the beginning of the twentieth century, Max Henius became interested in Danish-American organizations in Chicago. Funds were being raised by Danish Americans to purchase 200 acres (0.81 km2) of heather-covered hills, located in part of Rold Forest (Danish: Rold Skov), Denmark’s largest forest. In 1912 Max Henius presented the deed to H.M. King Christian X as a permanent memorial from Danish Americans. Rebild National Park (Danish: Rebild Bakker) is today a Danish national park situated near the town of Skørping in Rebild municipality, Region Nordjylland in northern Jutland, Denmark. Every July 4 since 1912, except during the two world wars, large crowds have gathered in the heather-covered hills of Rebild to celebrate American Independence Day. On the slope north of Rebild, where the residence of Max Henius was once located, a bust was placed in his memory.

wahl-and-henius

And here’s Randy Mosher’s entry from the Oxford Companion to Beer of the Wahl-Henius Institute of Fermentology:

Wahl-Henius Institute of Fermentology
is a brewing research laboratory and school in Chicago that operated between 1886 and 1921.

Founded in 1886 by Dr Robert Wahl and Dr Max Henius as the Wahl & Henius, the name was changed to the Scientific Station for Brewing of Chicago and then to the Institute of Fermentology before becoming the Wahl-Henius Institute. Its educational division, the American Brewing Academy, was created in 1891.

The school and laboratory operated successfully until Prohibition, when the near dissolution of the brewing trade forced its closure and sale to the American Institute of Baking, which retains the nucleus of the Wahl-Henius library.

Wahl-Henius would perhaps be mostly forgotten today if it were not for its role as publisher of two important beer texts. The Wahl-Henius Handy Book of Brewing, Malting and the Auxillary Trades, coauthored by Wahl and Henius, is a comprehensive and wide-ranging view into American brewing in 1901. It also contains basic chemical analyses of many contemporary American and European beers, providing an unusually valuable window into the brewing past. J. P. Arnold’s 1911 Origin and History of Beer and Brewing is an exhaustive romp through thousands of years of beer history.

Henius-bust
And this bust of Henius is in the Rebild National Park in Denmark. Henius organized fund-raising and “in 1911, almost 200 acres of the hilly countryside were bought with funds raised by Danish Americans. In 1912, Max Henius presented the deed to the land to his Majesty King Christian X as a permanent memorial to Danish Americans. Later the Danish government added to the land, that now features a beautiful natural park.”

And this is from the Chicago Midwest Rebild Chapter:

As we celebrate the 100th anniversary of the Rebild Society, I find it fascinating to look at the lives of its builders in the context of their times. It is hard to imagine a more dynamic time of porous borders and explosive growth than the late 19th century. Probably the name most closely associated with the founding of the Rebild Society is Max Henius. I had the good fortune to come across a biography of Henius written by his associates shortly after his death, and much of what I have written of Henius is largely based on that biography.

The first Europeans to come to Chicago were Pere Marquette and Louis Joliet in 1673 when they claimed Midwestern North America for Nouvelle France. Marquette and Joliet traveled up the Illinois River and portaged to the Chicago River and down to Lake Michigan. Joliet called for a canal to be built to connect the Illinois and Chicago rivers to stimulate trade and help France establish an economic empire in the New World. It was a prescient recommendation. Such a canal would indeed be built almost 200 years later, and an economic empire was ignited. Chicago would become the transport hub for a new nation, and not for New France.

In 1838, ten years before the canal was built connecting the Great Lakes and Mississippi watersheds, Max Henius’ father immigrated to Denmark from an impoverished Jewish family in Torun, Poland, traveling on foot to Aarhus, where his brother Jacob lived. The journey took six weeks. The elder Henius rose quickly in the distillery business first in Aarhus and then in København. He launched his own his distillery, Spritfabrikken in Aalborg in 1846, with money loaned from partners. In 1854 he returned to Torun to find a bride.

Born in 1859, Max was educated at the Aalborg Latin School and went on to study at the Polytechnic Institute in Hanover before matriculating at the University of Marburg, Germany. 1881 was a pivotal year for Max Henius. His father sold the distillery that Max had hoped to take over, and he had fallen in love with Johanne Heiberg. Both families disapproved of the relationship and Max Henius decided to immigrate to the US and subsequently send for his fiancée to come and marry him. Interestingly, a contemporary who would also become a very famous Danish-American, Jens Jensen, would immigrate to the US three years later partly because his prospective partner also did not meet family approval. A fellow student from Hannover and Warburg, Robert Wahl, told Max of the multiple opportunities available in the US, and later would partner with Henius in a very successful business.

Already in 1870 immigrants made up a larger proportion of the city’s population (48 percent) than any other place in North America. Chicago was quickly rebuilding after its massive destruction by fire in 1871 and Danish immigration was beginning to swell. Max Henius arrived in Chicago in October of 1881. Although he was a well educated and degreed chemist, his first jobs were as a door to door book salesman, errand boy for a pharmacy, and as a coal trimmer. Two years later he was employed by the Northern Pacific Railway to test the waters between Fargo, North Dakota and Bozeman, Montana but returned to Chicago to marry Johanne on June 4, 1883. With his savings he opened a drug store and subsequently formed Wahl & Henius, Analytical and Consulting Chemists with a lab at the back of the store. They established themselves as authorities on yeast culture and brewing.

Chicago was at this time one of the most rapidly growing cities in the world, the Shanghai of the late 19th century. Population growth was meteoric, fueled by decade after decade of immigration. But it was a wide open and divided city and hardly immune to the controversies of its time. May 1, 1886 saw a massive demonstration by workers (well advertised in the immigrant press) in favor of the eight-hour working day. Three days later the conflict culminated in a violent confrontation. The 1886 Haymarket Massacre took place in Chicago when an unknown person threw a dynamite bomb at police as they dispersed a public meeting. Chicago police fired on workers during a general strike for the eight-hour workday, killing several demonstrators and resulting in the deaths of several police officers. International Workers’ Day is the commemoration of the Haymarket Massacre. Ironically this would become a holiday officially celebrated throughout the Soviet bloc in the next century.

Henius did become involved in some of the public issues of this time. In 1892 a typhoid epidemic broke out in Chicago. Sewage was discharged into the Chicago River and subsequently found it way into Lake Michigan where Chicago’s water supply was tapped. Henius examined milk samples that were watered down and publicly spoke out on his findings. The waters of Lake Michigan were mapped bacteriologically so the water cribs were moved farther out in Lake Michigan.

Henius was very active in various Danish immigrant organizations, including the Danish-American Association, formed in Chicago in 1906. The idea for a Danish-American festival to be held in Denmark actually came from Ivar Kirkegaard, a Danish-American poet and editor. The first Danish-American rally was held in 1908 at Krabbesholm Folk High School on Skive Fjord. En route to the Krabbesholm festival, Henius was visiting Aarhus, when he learned of the planning for a national exposition to be held in Aarhus the following summer. He proposed to his fellow association members that they organize a Danish-American meeting for July 4, 1909. They filled an auditorium and persuaded the crown prince, later King Christian X, Georg Brandes and other noted Danes to speak at the event. Three years later Rebild Park was purchased by Danish Americans and set aside as a park, with the understanding that the site would be used to celebrate the 4th of July. Rebild Park was dedicated in 1912, and the first festival in Rebild was held on August 5, 1912.

Later Henius would found and head the Jacob A. Riis League of Patriotic Service to act as a clearing house for patriotic activities for Danish Americans during the First World War. The League grew out of a committee that managed the 3rd Liberty Load drive in Chicago among Danish-Americans. It also had among its objectives the preservation of Danish culture in America. Its influence was used with President Woodrow Wilson to include the question of the Danish border with Germany in the post war peace settlement. Henius would also be instrumental in establishing and supporting the Danes Worldwide Archives in Aalborg, initially housed in his childhood home of Sohngårdsholm.

Immigration has always been a controversial subject and resisted with varying degrees of success throughout history. But looking backwards one can only conclude it has been to our good fortune, and that our societies have been quite enriched and rejuvenated by the dynamism that immigrants have brought to us.

Henius-classroom
Henius-classroom-caption

And Gary Gillman also has a nice overview of Henius’ life in a blog post a few years ago, entitled Max Henius, Star of American Brewing Science.

Filed Under: Birthdays, Just For Fun, Related Pleasures Tagged With: Chicago, Denmark, History, Science of Brewing

Historic Beer Birthday: William S. Gossett

June 13, 2024 By Jay Brooks

guinness-new
Today is the birthday of William Sealy Gosset (June 13, 1876–October 16, 1937). He “was an English statistician. He published under the pen name Student, and developed the Student’s t-distribution.” He also worked his entire career for Guinness Brewing, and was trained as a chemist, but it was his pioneering work in statistics, in which he was self-taught, that he is remembered today.

William_Sealy_Gosset

Here’s his biography, from Wikipedia:

Born in Canterbury, England to Agnes Sealy Vidal and Colonel Frederic Gosset, Gosset attended Winchester College before studying chemistry and mathematics at New College, Oxford. Upon graduating in 1899, he joined the brewery of Arthur Guinness & Son in Dublin, Ireland.

As an employee of Guinness, a progressive agro-chemical business, Gosset applied his statistical knowledge – both in the brewery and on the farm – to the selection of the best yielding varieties of barley. Gosset acquired that knowledge by study, by trial and error, and by spending two terms in 1906–1907 in the biometrical laboratory of Karl Pearson. Gosset and Pearson had a good relationship. Pearson helped Gosset with the mathematics of his papers, including the 1908 papers, but had little appreciation of their importance. The papers addressed the brewer’s concern with small samples; biometricians like Pearson, on the other hand, typically had hundreds of observations and saw no urgency in developing small-sample methods.

Another researcher at Guinness had previously published a paper containing trade secrets of the Guinness brewery. To prevent further disclosure of confidential information, Guinness prohibited its employees from publishing any papers regardless of the contained information. However, after pleading with the brewery and explaining that his mathematical and philosophical conclusions were of no possible practical use to competing brewers, he was allowed to publish them, but under a pseudonym (“Student”), to avoid difficulties with the rest of the staff. Thus his most noteworthy achievement is now called Student’s, rather than Gosset’s, t-distribution.

Gosset had almost all his papers including The probable error of a mean published in Pearson’s journal Biometrika under the pseudonym Student. It was, however, not Pearson but Ronald A. Fisher who appreciated the importance of Gosset’s small-sample work, after Gosset had written to him to say I am sending you a copy of Student’s Tables as you are the only man that’s ever likely to use them!. Fisher believed that Gosset had effected a “logical revolution”. Fisher introduced a new form of Student’s statistic, denoted t, in terms of which Gosset’s statistic was {\displaystyle z={\frac {t}{\sqrt {n-1}}}} z=\frac{t}{\sqrt{n-1}}. The t-form was adopted because it fit in with Fisher’s theory of degrees of freedom. Fisher was also responsible for applications of the t-distribution to regression analysis.

Although introduced by others, Studentized residuals are named in Student’s honour because, like the problem that led to Student’s t-distribution, the idea of adjusting for estimated standard deviations is central to that concept.

Gosset’s interest in the cultivation of barley led him to speculate that the design of experiments should aim not only at improving the average yield but also at breeding varieties whose yield was insensitive to variation in soil and climate, i.e. robust. This principle only appeared in the later thought of Ronald Fisher, and then in the work of Genichi Taguchi during the 1950s.

In 1935, Gosset left Dublin to take up the position of Head Brewer, in charge of the scientific side of production, at a new Guinness brewery at Park Royal in northwestern London. He died two years later in Beaconsfield, England, of a heart attack.

Gosset was a friend of both Pearson and Fisher, a noteworthy achievement, for each had a massive ego and a loathing for the other. He was a modest man who once cut short an admirer with the comment that “Fisher would have discovered it all anyway.”

t-test-slide

And this biography is from the MacTutor History of Mathematics archive:

William Sealey Gosset was born on June 13, 1876 in Canterbury, England where he was the oldest of five children. He died at the age of 61 in Beaconsfield, England on October 16, 1937. He attended the Royal Military Academy in Woolwich to b ecome an engineer before he was rejected because of poor eyesight. William Gosset was never employed as a statistician. In a world of quarrelsome statistics, but he got along with everyone. He was a very helpful, quiet, patient and loyal person.

He went to school at Winchester and was well educated before entering the New College in Oxford. Here he won a first degree in chemistry in 1899. After getting his degree as a chemist, he got a job at Guinness brewery in Dublin in 1899, where he did important work on statistics, but her was never hired at a statistician. It was his environment at Guinness’ that made him a statistician. The brewery was interested in how they could make the best beer.

In 1900, the Guinness Research Laboratory was opened, which was head by the most distinguished brewing chemist, Horace Brown. Horace Brown along with the other brews were wondering how to get the raw materials for brewing beer at the cheapest but getting the best. There were many factors that they had to take into account such as varieties of barley and hops, what conditions of dying, cultivation and maturing factors.

After a few years of research, given that they were given a free hand to explore the conditions of brewing. This gave Gosset a chance to work as a statistician. He was able to take the data from the different examples of brewing to help find out which way was the best. As the young brewers work together, it seemed natural for them to take the data to Gosset to solve the numerical problems.

Gosset, in 1903, could calculate standard errors. In 1904 he wrote on the brewing of beer. This report lead to Karl Pearson consulting Gosset. Gosset met Pearson in July of 1905 when they had long talk together. Pearson, in an hour and a half, m ade Gosset understand the theory of standard errors. Gosset went back to the brewery and practiced those method for the next year. The meeting was also successful in which Pearson got Gosset to take up the study of the law of error.

Gosset wrote paper in his spare time under the name “Student.” His paper were on the probability of error of the mean and of the correlation coefficient for publication. Gosset even managed to run cooperative experiments with Hunter a nd Bennett at Ballinacurra, Buffin at Cambridge, and Beaven at Warminster in the testing of seeds against other seeds. Gosset also work with R.A. Fisher. The funny part is that Fisher did not get along Pearson, but Gosset studied under Pearson and also got along with Fisher.

To quickly recap William Gosset, he was born in 1876 and died in 1937. He did mathematical research for beer brewing, but had the problem working with only a small sample size. He work on the concept of probable errror of a mean. He also analysi sed an extended and broad range of problems such as the counting with a haemacytometer, probable error of a correlation coefficient, cereals, agronomy and the Lanarkshire milk experiment.

A very personal friend, McMullen, said this about Gosset, “he was a very kindly and tolerant and absolutely devoid malice. He rarely spoke about personal matters but when his opinion was well worth listening to and not in the least superficia l.”

Pricenomics has a good overview of Gossett’s contributions to mathematics and statistics, entitled The Guinness Brewer Who Revolutionized Statistics.

Filed Under: Birthdays, Just For Fun, Related Pleasures Tagged With: England, Guinness, History, Ireland, Math, Science, Science of Brewing

Historic Beer Birthday: Carl von Linde

June 11, 2024 By Jay Brooks

frig
Today is the birthday of Carl Paul Gottfried Linde (June 11, 1842–November 16, 1934). He “was a German scientist, engineer, and businessman. He discovered a refrigeration cycle and invented the first industrial-scale air separation and gas liquefaction processes. These breakthroughs laid the backbone for the 1913 Nobel Prize in Physics. Linde was a member of scientific and engineering associations, including being on the board of trustees of the Physikalisch-Technische Reichsanstalt and the Bavarian Academy of Sciences and Humanities. Linde was also the founder of what is now known as The Linde Group, the world’s largest industrial gases company, and ushered the creation of the supply chain of industrial gases as a profitable line of businesses. He was knighted in 1897 as Ritter von Linde.”

Carl_von_Linde_1868

His importance to brewing, especially yo lager beers, is undeniable. His first refrigerating machines were built for breweries. This is situation prior to his inventions, from the University of Chicago:

Before the development of mechanical refrigeration technologies, brewers were reliant on ice harvested from lakes and ponds and stored in ice-houses. The invention of mechanical refrigeration machines provided commercial brewers with the technology necessary to keep beer for longer periods of time. Refrigeration technology was also used in special railroad boxcars, permitting brewers to ship their product over longer distances. One of the most successful early designs for a mechanical refrigeration system was invented by Carl von Linde (a professor at Munich Polytechnic School) and was an ammonia-based vapor-compression system.

eCopy, Inc.
One of the drawing from his first patent, in 1873.

This history of the development of Linde’s refrigeration machines is from a brochure prepared by his the company he founded, The Linde Group.

Initial contacts with breweries

After von Linde had published his ideas in 1870 and 1871 in the Polytechnic Association’s “Bavarian Industry and Trade Journal,” which he also edited, a development was set in motion that would determine the direction of the entire rest of his life. His articles on refrigeration technology had aroused the interest of brewers who had been looking for a reliable year-round method of refrigeration for the fermentation and storage of their beer. In the summer of 1871 an agreement was made between von Linde, Austrian brewer August Deiglmayr (Dreher Brewery) and Munich brewer Gabriel Sedlmayr to build a test machine according to Linde’s design at the Spaten Brewery. With their help, Linde’s ideas would be put into practice, so that a refrigeration unit could then be installed at the Dreher Brewery, the largest brewery in Austria, in the hot, humid city of Trieste (now part of Italy).

Building the first Linde ice machine

The construction plans were finally completed in January 1873 and the patent applied for. The Bavarian patent required, however, that the machine be in operation within one year. Therefore von Linde and Sedlmayr placed an order with Maschinenfabrik Augsburg that same month to build it. And with some effort they succeeded in starting operation by the important patent deadline in January 1874. Of course, the first machine did have its difficulties.

The main problem was that von Linde’s mercury seal did not work properly so that the methyl ether used as the refrigerant leaked out of the compressor. In Linde’s words, “This design was not a suitable solution for the requirements of practical use. So it seemed imperative to build a second machine.”

In order to finance it, von Linde assigned part of the patent rights to Sedlmayr, to locomotive builder Georg Krauss and to the director of Maschinenfabrik Augsburg, Heinrich von Buz. In return, they provided the funds needed for the development, building and testing of a new refrigeration machine.

linde-refrigeration-machine

Building the second refrigeration machine

With his student and assistant Friedrich Schipper, von Linde designed a new compressor, which had a significantly simpler and more effective seal. The sealing material used in the newly designed gland construction was glycerin and the more efficient ammonia was used as the refrigerant. The new machine weighed and cost only half as much as its predecessor.

In the spring of 1875 Linde ordered the new compressor from Maschinenfabrik Augsburg and submitted it for a Bavarian patent, which was awarded on March 25, 1876 for ten years. He received the German Reichspatent in August 1877.

“The very first trials with this second compressor yielded fully satisfactory results,” said von Linde, not without pride. The machine was sold to the Dreher Brewery in September 1876, erected under Schipper’s supervision and started up in spring 1877. It ran until 1908, providing refrigeration and dehumidification

Technical breakthrough

But despite this success, Linde created a third design immediately after the second machine was installed at Dreher, turning his attention to gas pumps, which were already widely used. This third, horizontal design proved to be the best cold vapor machine on the market in terms of its price/performance ratio and became the standard type of Linde compressor for decades to come. During the more than six-year development and experimentation phase, a reliable solution also had to be found for distributing the generated cold. After long trials, in executing an order for the Heineken Brewery in Rotterdam, von Linde developed a method of circulating cold saltwater brine in a pipe cooling system (natural convection cooling), which was installed on the ceiling of the refrigeration rooms.

horizontal-twostage-ammonia-compressor

And this inset is about the company’s “First customers and partners: brewers.”

In 1840, many continental European breweries switched to bottom fermented lager production (in contrast to the “English” top-fermented brown beers or ales) because the beer remained fresh longer and customers preferred the taste. The ice machine described by von Linde seemed ideal for achieving the required lower temperatures and to ensure precise cooling control. So it is no wonder that some major brewers showed great interest in this invention.

Gabriel Sedlmayr of the Munich Spaten Brewerey was willing to let von Linde experiment with an early refrigeration machine in his brewery in the early 1870s. The first unit functioned passably well, but was too large and had numerous flaws. The drawings submitted for the patent showed that Sedlmayr himself had a hand in the second version, which was significantly smaller in size and worked well. This unit was sold to the Trieste Dreher Brewery for air cooling.

With Sedlmayr as an intermediary, the Rotterdam Heineken Brewery under its director Feldmann ordered an ice machine in 1877 for ice production. In his collaboration with the Heineken Brewery, Linde developed “natural convection cooling” with a system of cooling pipes under the ceiling of the cellar. Feldmann in turn put von Linde in contact with J. C. Jacobsen, head of the Carlsberg Brewery in Copenhagen, who ordered a large refrigeration unit in 1878.

Karl Lang, technical adviser and supervisory board member of several Rhineland breweries, also played a significant role during the founding period of the “Gesellschaft für Linde’s Eismaschinen.” He introduced Linde to brewery director Gustav Jung, who not only ordered a refrigeration unit but also became, with Lang and banker Moritz von Hirsch, a shareholder and Supervisory Board member of the Linde Company.

The connection between the Linde Company and brewery directors was maintained to some extent over several generations. After the death of Karl Lang in 1894 his position as chairman of the Supervisory Board was taken over by Gustav Jung, followed by his son Adolf Jung in 1886. Carl Sedlmayr took over for his father Gabriel on the Supervisory Board and in 1915, the third generation of this family followed with Anton Sedlmayr. The Jung and Sedlmayr families held their Supervisory Board seats until after the Second World War.

Dr.Carl-von-Linde-1925

Here’s Linde’s entry from the Oxford Companion to Beer, written by Horst Dornbush.

Linde, Carl von
was a 19th-century German engineer and one of the world’s major inventors of refrigeration technology. See refrigeration. Starting in the middle of the 18th century, many people before Linde had tinkered with artificial refrigeration contraptions, but Linde was the first to develop a practical refrigeration system that was specifically designed for keeping fermenting and maturing beer cool—in Linde’s case, Bavarian lagers—during the hot summer months. Linde was born in the village of Berndorf, in Franconia, in 1842, at a time when warm-weather brewing was strictly forbidden in his native Bavaria; no one was allowed to brew beer between Saint George’s Day (April 23) and Michael’s Day (September 29). This was to avoid warm fermentations, which provided ideal habitats for noxious airborne bacteria to proliferate and caused yeasts to produce undesirable fermentation flavors. Both made summer beers often unpalatable. Summer brewing prohibition had been in force since 1553 and was only lifted in 1850, by which time Bavarian brewers had learned to pack their fermentation cellars with ice they had laboriously harvested in the winter from frozen ponds and lakes. There had to be a better way to keep beer cold…and that was just the challenge for a budding mechanical engineering professor like Linde, who had joined Munich’s Technical University in 1868. See weihenstephan. The basic principle of refrigeration had been understood for centuries. Because cold is merely the absence of heat, to make things cold, one must withdraw heat. Compressing a medium generates heat; subsequently decompressing or evaporating it quickly absorbs heat from its environment. Devices based on this principle are now generally known as vapor-compression refrigeration systems; apply this to a fermenting or lagering vessel, and it becomes a beer-cooling system. For Linde, the next question was the choice of refrigerant. Initially he experimented with dimethyl ether but eventually settled on ammonia because of its rapid expansion (and thus cooling) properties. He called his invention an “ammonia cold machine.” Linde had received much of the funding for this development from the Spaten Brewery in Munich, which was also the first customer to install the new device—then still driven by dimethyl ether—in 1873. By 1879, Linde had quit his professorship and formed his own “Ice Machine Company,” which is still in operation today as Linde AG, headquartered in Wiesbaden, Germany. By 1890, Linde had sold 747 refrigeration units machines to various breweries and cold storage facilities. He continued to innovate and invented new devices most of his life, including equipment for liquefying air, and for the production of pure oxygen, nitrogen, and hydrogen. In 1897 he was knighted, and from then on could append the honorific “von” to his surname. He died a prosperous industrialist in Munich in 1934, at the age of 92, and today Linde AG is a leading gases and engineering company with almost 48,000 employees working in more than 100 countries worldwide. For all his many accomplishments, Linde’s pioneering work in artificial beer cooling technology is perhaps his most enduring legacy.

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Filed Under: Birthdays, Just For Fun, Related Pleasures Tagged With: Germany, History, Science, Science of Brewing

Beer In Ads #3832: A Good Pretzel Has A Lot Of Salt. A Good Beer Has Just A Little.

August 29, 2021 By Jay Brooks

Sunday’s ad is for “Rainier Beer,” from the 1970s. This ad was made for the Seattle Brewing & Malting Co., who made Rainier Beer, and was later known as the Rainier Brewing Company of Seattle, Washington. This one features an eye-catching giant pretzel that fills the page. Below that is the tagline. “A good pretzel has a lot of salt. A good beer has just a little.” And below that, the text explains that Rainier’s brewers add a pinch of salt to the water.

Filed Under: Art & Beer, Beers Tagged With: Advertising, History, Science of Brewing, Washington

The Secret Life of Machines: Adnams Brewery

January 1, 2018 By Jay Brooks

animated-tim
A favorite British television show of mine was The Secret Life of Machines, by Tim Hunkin, whose birthday is today, January 1, 1950. Hunkin is “an English engineer, cartoonist, writer, and artist living in Suffolk, England. He is best known for creating the Channel Four television series The Secret Life of Machines, in which he explains the workings and history of various household devices. He has also created museum exhibits for institutions across the UK, and designed numerous public engineering works, chiefly for entertainment. Hunkin’s works are distinctive, often recognisable by his unique style of papier-mâché sculpture (made from unpainted newsprint), his pen and ink cartoons, and his offbeat sense of humour.” Given that his show, three seasons between 1988-1993, was about how machines work, it’s surprisingly low-key and minimalist, but quite fascinating. And often very funny.

Anyway, in 1977, Adnams Brewery, commissioned Hunkin to create a poster of their brewery in Suffolk. Hunkin remembered. “I spent a month drawing it and so enjoyed the experience that I moved out of London to Suffolk where I’ve lived ever since. I didn’t even drink much of the beer at the time. Before drawing it, I don’t think I had ever appreciated how the combination of words and drawings can make conveying information much clearer and simpler. I was able to dramatically cut the text about the brewing process by having it integrated with the drawing of the vats and pipes. I think all journalists should be taught to draw.”

I have a couple of books by Hunkin that are filled with detailed doodle drawings with loads of text like this, and they’re great, so I’d love to see what he wrote in this poster although the biggest file of the poster I could find wasn’t quite big enough to read it all.

adnams_brewery-poster
Or you can see it full size here.

Filed Under: Art & Beer, Breweries, Just For Fun, Related Pleasures Tagged With: England, Great Britain, History, Science of Brewing

We Do More Than Just Brew Beer

January 2, 2017 By Jay Brooks

brewhouse
This is a fun piece of illustration, an infographic New Year’s Eve card of sorts, commissioned by Baltika, which is a Russian brewery that’s part of the Carlsberg Group. They hired Anton Egorov to create something like Мы больше, чем просто варят пиво, which is a reverse translation of their English version of the infographic, “We Do More Than Just Brew Beer.” Egorov completed it in December of 2014, so presumably they used it in either 2015 or 2016, since according to the artist’s description, his illustrations were for a corporate calendar. That’s one I would have liked.

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Filed Under: Art & Beer, Breweries, Just For Fun, Related Pleasures Tagged With: Infographics, Russia, Science of Brewing

Patent No. 5077061A: Method Of Making Alcohol-Free Beer

December 31, 2016 By Jay Brooks

patent-logo
Today in 1991, US Patent 5077061 A was issued, an invention of Christian Zurcher and Rudiger Gruss, assigned to Binding-Brauerei Ag, for their “Method of Making Alcohol-Free or Nearly Alcohol-Free Beer.” Here’s the Abstract:

A method of producing an alcohol-free or low alcohol beer comprising thermally breaking malt draff to obtain a malt draff mash from a substrate selected from the group consisting of a full- or a high-alcohol content beer brewing base or a protein fraction obtained from malt draff by digesting, boiling or autoclaving during the production of edible draff meal in a draff mash. The method homogenizes, extrudes and mechanically removes insoluble chaff from the brewing base prior to thermally breaking up the malt draff, cooling the malt draff mash to about 72° C., emzymatically breaking up the malt draff mash by adding coarsely ground malt, heating the mash to 80°-85° C., adding thereto coarsely ground malt premashed in cold water to produce a wort with a final fermentation degree of at most 60% and a temperature of 70°-74° C., which is maintained until iodine normality is attained and subjecting the iodine normal mash to mashing.

I’ve visited the brewery in Frankfurt, and done several blind panel tastings of N/A beer, and Clausthaler consistently comes in at our near the top. Also, it was our best-selling non-alcoholic when I was the chain beer buyer at BevMo. too.
clausthaler

Filed Under: Beers, Breweries, Just For Fun, Politics & Law, Related Pleasures Tagged With: History, Law, Patent, Science of Brewing

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